Bituminous paving emulsions



United States Patent 3,422,026 BITUMINOUS PAVING EMULSIONS James R. Wright, Bethesda, Md., assignor to Chevron Research Company, San Francisco, Calif a corporation of Delaware No Drawing. Continuation-impart of application Ser. No. 103,823, Apr. 18, 1961. This application Apr. 6, 1965, Ser. No. 446,118 US. Cl. 252-3115 2 Claims Int. Cl. B013 13/00; C09d 3/24 ABSTRACT OF THE DISCLOSURE An oil-in-water type paving emulsion of 50 to 75% by weight of asphalt emulsified in water with the aid of a combination of cation-active and ampholytic emulsifiers, wherein from 0.025 to 0.25% by weight is an ampholytic emulsifier whose isoelectric point lies on the acid side of the neutral point. The pH of the emulsion is on the acid side, and the ampholytic component of the emulsifier combination contains at least one aliphatic C -C hydrocarbon chain, and at least one basic nitrogen atom, and at least one acid radical.

The present invention relates to aqueous bituminous emulsions suitable for seal-coating work in the construction and repair of roads, aerodromes and other ground surfaces, and more particularly it relates to oil-in-water type asphalt emulsions suitable for the aforementioned coating applications.

This application is a continuation-inpart of my copending application Ser. No. 103,823, filed Apr. 18, 1961 and presently abandoned.

Anionic bituminous emulsions available on the market for various road-paving uses ordinarily are prepared by heating a bitumen, such as asphalt, to a liquid state and then thoroughly agitating it with hot water in the presence of an anion-active emulsifier dissolved in the water as such, or yet formed in situ in the course of agitation, owing to the addition to the water-asphalt mixture of an alkaline base which reacts with the acid constituents of the asphalt.

Cationic bituminous emulsions, e.g., asphalt-in-water emulsions, more recently introduced on the market, are formed by a similar agitation of melted asphalt with water with the aid of cation-active emulsifiers which are either dissolved in the water employed for emulsification, or are dispersed in the asphalt phase before the emulsification, or yet emulsification may be carried out in situ, treating the asphalt with a base, such as an amine, and then dispersing the treated asphalt in a dilute solution of a water-soluble acid, such as hydrochloric.

Many factors are apt to influence the success of application of bituminous emulsions in paving work, one of the most important being the nature of the stone aggregate with which the emulsion is being mixed, or on which it is applied, on the job. When electro-positive aggregates, such as dolomite or limestone, are not available, and siliceous materials, such as quartz or sandstone chips, sand, and the like, are to be used instead, anionic emulsions do not provide an adequate coating of the aggregate, and the reulting paved surface lacks stability and strength and fails to endure. Conversely, cationic emulsions generally are ineffective on dolomite, limestone, and like stone aggregates.

Consequently, production of aqueous bituminous emulsions and, in particular, of asphalt-in-water paving emulsions, such as sea] coat emulsions, mixing-grade emulsions, and the like, which would within a fixed pH range be capable of coating satisfactorily both kinds of stone aggregates, the electro-positive and the electro-negative, as well as the aggregates of a mixed type (carrying both positive and negative surface charges), appeared heretofore to be a desirable, however, practically unattainable ideal.

I have now found that bituminous emulsions of such ambivalent character, that is, emulsions which provide an effective coating of the bituminous binder on either electro-negative or electro-positive stone aggregates can be readily prepared by using for the purpose a surfaceactive ampholytic or amphoteric material which effectively emulsifies bitumen in water. The resulting emulsions are suflicient-ly stable in storage and for handling prior to actual use, and furnish an adequate coating of the bituminous or asphaltic binder on stone aggregate, irrespective of the electric charges on the surface of the latter, provided the pH of these emulsions lies in the particular operative range which will be described hereinafter.

Particularly effective and, accordingly, preferred are those ampholytic materials (ampholy-tes) whose isoelectric point lies on the acid side of the neutral point (pH-=70). By adjusting and maintaining the pH of the emulsions formulated with the aid of such ampholytes to a value that is less than about pH=7.0, one is enabled to obtain an effective coating of bitumen (asphalt) on either a siliceous (electro-negative) or a limestone (electro-negative) aggregate.

The pH of the emulsifying water may be adjusted in advance, prior to emulsification, with the aid of either an acid or a base, to provide to the finished emulsion a pH that would permit effective coating of stone aggregates.

The operative and, accordingly, preferred pH range of the emulsions of my invention can extend from a value differing by about 0.25 pH units or from the value, in pH units, of the isoelectric point of a given ampholytic emulsifier, which has its isoelectric point on the acid side, to a value which is less than pH=7.0 and may be located as far as 3 pH units on either side of the isoelectric point of the ampholyte. Within this range of pH values, the emulsion can be used to obtain satisfactory coatings of either electro-negative or electro-positive aggregates. Preferably, the pH of the emulsion should lie within the range of values extending about 2.5 pH units on both sides of the isoelectric point of a given ampholytic emulsifier, but should not exceed pH=7.0.

The segment of the pH range extending 0.25 pH units on each side of the isoelectric point corresponds to that portion of the pH range where the ampholyte is present predominantly in the zwitter-ion form, the isoelectric point corresponding to the exact electrical neutrality (the number of anions being equal to the number of cations). This segment may be designated as the isoelectric range of the ampholyte.

Suppose, as an illustration, that, in accordance with the preferred aspect of my invention, an ampholyte has an isoelectric point on the acid side of the neutral point. At the isoelectric point and close to it, the electrophoretic mobility is substantially nil, the concentrations of positively charged and negatively charged ions being virtually equal. Beyond this narrow segment of electrophoretic inactivity (the so-called isoelectric range), which usually does not extend more than about 0.25 pH units on either side of the isoelectric point, and for as much as about 3.0 pH units, preferably about 2.5 pH units away from that point, so long as the pH of the emulsion of bitumen is on the acid side of the neutral point, the presence of comparatively high concentrations of both positively and negatively charged ions of the ampholyte in this emulsion of bitumen in water permits effective coating of oppositely charged stone aggregates.

When the surface-active ampholytic materials suitable for the preparation of the bituminous emulsions of the present invention are used as the sole emulsifiers to effectuate the emulsification of bitumen in water, their 3 amounts may range from about 0.15% to about 1.5%, and preferably from about 0.25% to about 1.0% (undiluted) by weight of the finished emulsion.

Particularly suitable and effective emulsifiers for preparing asphalt-in-water emulsions of the present invention are those surface-active ampholytes having their isoelectric point on the acid side of the neutral point, whose molecules are characterized by the presence of at least one aliphatic hydrocarbon chain of from 8 to 36 carbon atoms, preferably of from 8 to 4 carbon atoms, at least one basic nitrogen and at least one acid radical.

The basic nitrogen which must be present in the molecule of an ampholytic emulsifier effective according to the present invention may be either in the form of a quaternary or a non-quaternary nitrogen, for instance, a nitrogen of an ammonium, pyridinium, imidazolinium or amine group.

As illustrations of such suitable ampholytic emulsifiers, there may be mentioned, as particularly effective, higher C C -alkylamino carboxylic acids and their water-soluble salts, such as N-dodecyl-beta-imino-dipropionic acid, N-stearyl-beta-iminodiacetic acid, N octadecenylaminopropionic acid, N-hexadecylaminoacetic acid; also higher alkyl betaines, such as those in which the long-chain hydrocarbon group is attached to the carbon atom as, for example, in C-cetyl betaine represented by the formula:

COOH

Among the commercially available ampholytic surfaceactive materials which may be used to prepare asphalt and like bitumens in accordance with the invention, there may be mentioned:

(1) The various N-substituted aminocarboxylic acid derivatives obtained by the condensation of fatty primary amines and acrylic monomers. These derivatives are sold to the trade under the generic designation of Deriphats. Among these, N-fatty-beta-aminopropionates (Deriphats 151 and 170C) and N-fatty-beta-iminodipropionates (Deriphats 154 and 160C) are particularly effective for the purposes of this invention.

(2) The material known in the trade under the designation of BCO, a product of E. I. du Pont de Nemours & Co. (Inc.); it is a betaine corresponding to the formula of C-cetyl betaine given hereinabove.

(3) The several Miranols forming a group of trademarked materials which correspond to the general structural formula of:

in which R is a long hydrocarbon chain, for instance, a lauryl or an oleyl radical.

Ampholytic non-nitrogenous surfactants which contain sulfonium or phosphonium groups and have their isoelectric points on the acid side of the neutral point are similarly effective as emulsifiers for bitumen and improve the stone-coating property of the corresponding bituminous emulsions. An example of such a surfactants is thetine, described in US. Patent No. 2,178,353, issued to Werntz, and other like compounds. However, in view of their lower cost and availability, nitrogen-containing ampholytes are at present preferred.

Any bitumen capable of being emulsified in water with the aid of ampholytic materials of the kind described may be employed for preparing emulsions which will effectively coat both the electro-positive and the electro-negative stone aggregates in conformity with the principle of the invention. Asphalts are particularly suitable for the purpose, including both natural asphalts and refined asphalts, e.g., steam-refined asphalts, and the like. The asphalt-in-water emulsions prepared with the ampholytic emulsifiers in accordance with the invention may be of either the rapid-. setting, medium-setting or slow-setting type. They contain from about 50 to about 75% by weight of asphalt, preferably from about 55% to about 70% by weight of asphalt, the balance to make up 100% by Weight of the total emulsion being water and the emulsifier. This latter is used, as indicated before, in amounts which may range from about 0.15% to about 1.5% by weight, and preferably from about 0.25 to about 1.0% (undiluted) by weight of the finished emulsion.

In addition, I wish to emphasize at this point that so long as at least 0.025% by weight of the ampholytic surfactant is present in the emulsifier used for the emulsification of asphalt and similar bitumens, the resulting paving emulsions will provide a satisfactory coating of the bituminous binder on the aggregate. In fact, as much as about of the surface-active material necessary to emulsify the asphalt may be provided by cation-active quaternary ammonium halide salts (preferably chlorides) of certain fatty amines and polyethoxylated fatty amines. This permits reducing the quantity of the usually costlier ampholytic component by replacing it with a cheaper material, for instance, a cationic C C alkyl trimethyl ammonium compound sold under the trademark Arquad or with a likewise cationic polyethoxylated quaternary ammonium compound sold under the trademark Ethoquad. While thus securing a substantial reduction in the cost of the final paving emulsion, the presence of the ampholytic material, even though in small amounts from at least 0.025 by weight to about 0.25% by weight, in the total emulsifier combination still insures the desired amphoteric effect, enabling the coating of both electropositive and electro-negative aggregates in accordance with the invention.

Very effective and, therefore, satisfactory combinations of an ampholytic material with another emulsifier according to my invention are those which use an ampholyte, such as a Deriphat, BCO," oor a Miranol, and a polyethoxylated quaternary ammonium compound having one long alkyl group derived from C -C fatty acids on the quaternary nitrogen, and also having a total of oxyethylene units which may range from 2 to 50. The weight ratio of the ampholyte to the polyethoxylated compound may be from about 1:6 to about 1:4 (based on active materials). The polyethoxylated quaternary ammonium compounds referred to hereinbefore are available, for instance, in the trade under the trademark Ethoquad and have the following general structure:

in which R is a long alkyl chain derived from oleic, stearic or coco fatty acids and the sum of x and y can be from 2 to 15.

Very satisfactory results of coating the aggregate have been obtained with bituminous (asphalt) emulsions prepared with the aid of the combinations of ampholytes, such as Deriphat C and Deriphat 161, with the cationic salts of polyethoxylated quaternary ammonium materials sold under the trademark designations of Ethoquad 18/12, Ethoquad C/l2 and Ethoquad O/12. In this last-named material, the long alkyl chain is derived from oleic acid, and it contains two mols of ethylene oxide, the preferred weight ratio of the ampholyte (Deriphat 160C) to this particular Ethoquad being from about 1 to about 5 (based on 100% active materials).

No special technique is required for carrying out the emulsification, except that the pH of the aqueous phase of the emulsion is selected beforehand, so that the pH of the final emulsion would lie within the operative range on each side of the isoelectric point of the particular ampholytic emulsifier, excluding the short segment of isoelectric range. For this purpose, addition of a suitable amount of an acid or of a base may be necessary.

The resulting asphalt emulsions may be employed for all kinds of seal coat treatments, for base stabilization work and for the preparation of mixes with sand and the like stone aggregates to be used in paving.

Whenever desired, conventional additives known in the an asphalt content from about -62% to about 65% by weight. In this first series of tests, three ampholytic emulsifiers were employed: the amphoteric surfactant BCO (C-cetyl betaine) referred to hereinbefore which is a balanced ampholyte, i.e., one in which the number art of bituminous emulsions may be incorporated in the 5 of acidic groups equals the number of basic groups; also, emulsions in order to improve certain desirable properties two Deriphats of the trade, namely, Deriphat 151 which thereof. These additives include, for instance, anti-stripis sodium N-coco-beta-aminopropionate, likewise a baping agents, thickening agents, compounds which modify lanced ampholyte, and Deriphat 154 which is disodium (lower) the emulsion viscosity, such as sodium acetate 10 N-tallow-beta-iminodipropionate, an unbalanced am- (in amounts from about 0.10 to about 0.25% by weight), pholyte containing two carboxylic acid groups and one and additives which facilitate mixing with the aggregate, amine group. The prefixes coco and tallow indicate etc., the sole condition being that the presence of these the presence of hydrocarbon (alkyl) radicals derived additives would not affect adversely the beneficial charfrom coconut oil and animal tallow, respectively. The acteristics brought about by the use of ampholytic emulsiisoelectric point of each ampholyte was obtained by fiers. Likewise, addition of conventional hydrocarbon cutknown titration techniques. Where the a-mpholyte is too ter stocks, such as naphtha, and in such amounts as would sensitive to small amounts of acid or base, the paper strip not interfere with the operativeness and quality of the electrophoresis method or microelectrophoretic mobility emulsions, is also contemplated within the scope of the method may be substituted with success.

present invention. The pH of Deriphats in water solution is strongly In addition, the application of ampholytic compounds alkaline (of the order of 11. 0 pH units), and it was therein conjunction with the cationic emulsifying quaternary fore necessary to adjust the pH of the emulsifying water salts of fatty amines and polyethoxylated fatty amines, in their tests by the addition of an acid, preferably HCl. such as Arquads and Ethoquads for the preparation Viscosity of each emulsion in seconds at 122 F. was of asphalt-in-water emulsions for use in paving work acmeasured in a known manner (ASTM Method D244) in a cording to the present invention offers an unexpected solu- Saybolt-Furol viscometer. tion to the problem of securing satisfactory emulsion-sand Effective coating of different stone aggregates was mixes. Heretofore satisfactory mixes of cationic emulsions established by employing a special stone coating-water with sand were difiicult to obtain, particularly when the resistance testing technique, as follows: sand contained any appreciable proportion of fines. Prob- 0 465 g. of the aggregate washed, dried and graded to ably, this was due to the fact that cation-active materials pass a screen and be retained on a No. 4 screen, was are strongly attracted to hydrophilic sand particles and weighed into a metal pan about 8" in diameter and 3" that, accordingly, the emulsion becomes prematurely dedeep. Water in an amount of 9.3 g. was added into the stabilized (breaks too fast), while being mixed with sand. pan and mixed with a mixing spoon until uniformly dis- Also, it may well be that the cause of inadequate coating persed. Then 35 g. of the emulsion was weighed in the is the large total surface area of the particles of sand same pan and mixed with the stone aggregate, until this and their slickness, or yet the presence of appreciable latter became completely coated. The mix was allowed to amounts of fines may be the cause, or all of these factors cure in the pan for thirty minutes at room temperature. together may contribute to premature breakdown and in- After this cure and without remixing, the mixture was sufiicient coating. 40 washed in the pan with cold tap water until the overflow Particularly, when a combination of one of the afore- Water ran clear. The excess water was drained off and the mentioned Deriphats, e.g., Deriphat 160C, Deriphat mixture placed on absorbent paper for visual evaluation 161 or Deriphat 170C, with one of the Ethoquads, of the extent of coating of the stone surface. For seal preferably Ethoquad O/12, is used for the preparation coat work, coating of at least 75% of the surface is satisof emulsions of bitumen, the mixes of such emulsions with factory. Coating to the extent of 90% and higher is consand in the conventional proportions of the paving pracsidered to be excellent. In base stabilization work, the re tice (5 to 10% by weight of the emulsion) unexpectedly quirements are ordinarily less stringent and coating efdisplay a highly satisfactory coating of the particles, so fectiveness of may sometimes be considered acthat not less than 75 of the surface thereof becomes ceptable, depending on the nature of the aggregate (its coated with the bituminous binder from the emulsion. 50 size and shape), compactness of the base, etc.

For the purpose of illustrating the advantages of the The pH of the emulsions was adjusted below the emulsions prepared with ampholytic emulsifiers as deneutral point (pH-:70) but above the isoelectric range, scribed herein'above, and in order to confirm the eifecexcept, of course, in the case of two emulsions, an tiveness of these emulsions on stone aggregates bearing anionic and a cationic one, used for the purpose of comopposite electrical charges, numerous tests have been parison. The anionic emulsion was prepared by employconducted, and some of the representative results of these ing an anion-active potassium soap of tall oil acids as tests are being offered hereinafter. the emulsifier, while the cationic emulsion was prepared A number of emulsions have been prepared using two with the aid of a cation-active emulsifier, namely, the different kinds of asphalt, asphalt A having substantially C C -alky1 trimethyl ammonium chloride, sold in the no inherent acidity, and asphalt B, the acid value of which trade under the trademark Arquad T. The results of this ranged from about 1.0 to about 1.5 The emulsions had first series of tests are assembled in Table I below.

TABLE I Emulsifier pH of Asphalt Extent of Coating (Estimated in percent) Run Emulsi- Vise. in Number Amt. in I.E.P lying Amt. in SSF at Sand- Lime- Sili- Dolo- Name Weight in pH Water Type Weight 122 F. stone stone ceous mite Sand Percent Units Percent Gravel 3.0 A 05 10.0 A 5.5 B 02 10.0 B 02 3.0 B 02 5.5 B 05 5.5 B 62 6.5 B 02 5.5 B 02 B 65 Mixing time in the Stone-Coating Test was 120 see. on sand and sec. on Dolomite; in this test, 3%

mulsion.

oi naphtha cutter was added to preformed It is apparent from the data in Table I that the use Of ampholytic emulsifiers in accordance with the invention enables production of satisfactory coatings of asphalt on either the siliceous-type or the limestone-type aggregates (Run 1). When the pH of the emulsion is higher than the 8 cosity, and 0.05% of hydrochloric acid (20 B.), the acid being used to fix the pH of the emulsion at about 6.6.

The emulsion was then mixed with a rather difficult-tocoat sand which contained fines and some organic matter and was obtained from Dauphin Island in Alabama. The

value of the isoelectric point plus 3.0 pH units, an ade- 5 testing was done by the so-called Pan and Spoon quate coating is no longer obtained (Run 2, result on sand- Method in conformance with the following procedure: stone and Run 4, result on siliceous gravel). The runs 100 g. of sand dried in an electric oven at 140 F. rewhich employ emulsions prepared with ampholytic emulsiceived an addition of 5 g. of distilled water to simulate fiers in accordance with the invention, namely, Runs 1, 3, the average moisture content observed in dry sand. Then and 5 to 8 inclusive, clearly demonstrate the effectiveness the emulsion, containing, if desired, additional water or of these emulsions in coating both the electro-negative and cutter stock (naphtha or the like) was added to the sand the electro-positive stone aggregates. By contrast, the and mixed thoroughly therewith for about five minutes in cationic emulsion applied on limestone (Run 9) preformed a l6-ounce can, using a tablespoon to achieve complete y P y, y 2 of the f coming d, coating of the sand. Immediately thereafter, the mix was while the anionic emulsion employed on hydrophilic sand h ld und a tr m of w t r from th laboratory tap aggregate failed almost p tely, ly 5% 0f until the water ran clear. The percentage of the bitumithe surface becoming coated. nous binder which did not Wash 011 from the surface .of 111 Table i there are Presented results of another Serles the sand was then estimated visually. Table III presents of test runs with emulsions prepared using the ampholytic th lt f thre u h te t emulsifiers of the invention on opposite types of stone aggregates (limestone and silica). The data in this table again illustrate the advantages achieved by the invention. The same two asphalts A and B have been employed in TABLE III this series, the asphalt content of the final emulsion vary- Coming ing from about 62% to about 66% by weight. Test Com osmon of Mix Estimated Representative ampholytic emulsifiers were employed to p Quality Coverage make the emulsions. These emulsifiers included several 111 percent Deriphats and Miranols described hereinbefore. Efiective- A 8% emulsion, 5% water very good 9H5 ness of the emulsions in coating stone aggregates has been g again compared with a typical anionic and -a typical cation- B 3% emulsion, 5% water, 5% j 95+ ic emulsion. The procedures were the same employed in naphtha. the tests carried out to obtain the data shown in Table I. C 10% emulsion 10% water very 90 TABLE II Extent of Coating Emulsifier pH of Asphalt Visc. in (Estimated in Percent) Emulsi- SSF at Run Amt. in I.E.P. tying Amt. in 122 F. Number Name Weight in pH Water Type Percent Limestone Silica Percent Units 1... Deriphat 151 0.36 4. 25 1.6 B 65 95+ 95+ 2. Deriphat 154.... 0.208 4. 5.5 B 62 60 85 75 3. Deriphat 151.. 0.416 4. 25 5.5 B 65 210 70 75 4... 16 0. 312 4. 25 5.5 B 65 168 so 90 5 Deriphat 160C--. 0.666 4.25 5.5 B 62 75 85 60 Miranol OMSF* 0.66 5.1 2.0 A 65 65 so 85 d 0. 66 5. 1 3. 0 A 65 75 70 00 0. 66 5. 1 s. 0 A 65 70 65+ 85 0. 66 5. 1 7. 0 A 65 105 65 75 .332 4. 25 5.5 B 62 185 00 95 1 '4' 25" 6.5 B 62 127 05+ 01312 7.5 B 65 85+ 0. 30 5. 5 B 62 69s 25 95+ D h 1:154 822 10.0 B 65 90+ 5 en a 15 g 2 5. 5 B 62 410 75 90+ *Miranol OM-SF is a trademarked designation for the concentrate of one of the "Miranols referred to hereinbefore, in the general formula of which the radical R is a hydrocarbon radical derived from oleic acid.

*Dcriphat 1600 is a partial sodium salt of N-lauryliminodipropionate.

The results in Table II again clearly demonstrate the operativeness of the asphalt-in-water emulsions prepared with ampholytic emulsifiers in accordance with the invention. In addition, the data of Runs 10, 11 and 15 confirm the fact that combining ampholytic emulsifiers with cationic emulsifier does not nullify the desired amphoteric effect of the ampholyte component.

The effectiveness of ampholytic compounds when used in combination with cationic emulsifiers to make bituminous emulsions according to the invention, for the purpose of preparing paving mixes with sand, is illustrated by the following series of tests.

An emulsion was prepared by emulsifying 68% by weight of a Venezuelan asphalt Penetration) in water, using 0.7%, based on the weight of the final emulsion, of Ethoquad O/l2, and 0.2% of Deriphat 1600. In addition, the emulsion contained 0.2% by weight of anhydrous sodium acetate to reduce the vis- In another series of tests the emulsion had the following composition: 68% of the same Venezuelan asphalt as in the emulsion of Table III, 0.5% of Ethoquad O/ 12, 0.2% of Deriphat 160C, 0.15% of anhydrous sodium acetate and enough hydrochloric acid to bring the pH down from 6.8 to 5.0. Amounts equal to 8 and 10%, respectively, of this emulsion were used for mixing with the sand, which was a sand of Maryland origin containing about 2% of fines and 5% moisture. The mixing was carried out in a pug mill, and a 100-gallon batch of emulsion was used in making the sand mix laid on a pavement test strip exposed to considerable truck traffic. The coating of sand was found to be good to Admixture of from 5 to 10% of cutter stock (naphtha) in the emulsifying water appeared to have no adverse effect on the coating performance. Although, immediately following the placing of this sand mix, it rained, no washotf was observed.

Still in another series of emulsion-sand mixes, the emulsion composition was 68% of a Venezuelan asphalt with a penetration value equal to 193; 0.7% of Ethoquad O/12, 0.28% of Deriphat 160C, and 0.049% of hydrochloric acid (20 B.), the balance to 100% by weight being water. The emulsion, in addition, received 10% of naphtha and had a pH of 5.5. The samples for testing emulsion-sand mixes were prepared by mixing together for five minutes 100 g. of sand and 10 g. of the emulsion plus 5 g. of water. The sand was a typical fine sand of Minnesota origin. When the coating was observed, after the sample was first cooled for thirty minutes and then washed, it appeared to be excellent in texture and was estimated to cover more than 90% of the surface of sand particles.

In still another series of tests, the emulsion was prepared using again 68% of a Venzuelan asphalt (Penetration 200), emulsified in water with 0.5% of Ethoquad O/12 and 0.2% of Deriphat 160C. Additionally, it contained 0.15% of sodium acetate and 0.038% of hydrochloric acid, the balance (31.11%) being water. The pH of this emulsion was 5.7. When mixes with sands of Florida and Alabama origin were prepared, good coating was observed, estimated to cover from 75 to 90% of the sand surface.

Thus, as shown in the preceding description and experimental test data, the invention permits of providing the paving industry with a versatile type of emulsion which can be used satisfactorily to coat different stone aggregates (different as regards the electric charges of the stone surface). These emulsions are prepared by employing ampholytic emulsifiers and selecting the pH range that will provide the optimum coating of either stone aggregate.

It is, of course, to be understood that the invention as described hereina'bove is not limited 'by the recitals of the particular ampholytic emulsifiers in the description and the illustrative examples, and that all modifications which do not depart from the scope of the invention are to be comprised within the coverage of the attached claims.

I claim:

1. An oil-in-water type paving bituminous emulsion having its pH on the acid side of the neutral point and consisting essentially of from about to about by weight of asphalt; and, as an emulsifier for said asphalt in water, from about 0.15 to about 1.5% by weight of the combination of (1) a cation-active emulsifying salt selected from the group consisting of quaternary ammonium salts of C -C fatty amines and polyethoxylated C -C fatty amines and (2) an ampholytic emulsifying salt selected from the group consisting of water-soluble sodium salts of C -C alkyl beta aminopropionic and C -C alkyl beta-iminodipropionic acids, the weight ratio of ampholytic emulsifying salt to the cation-active emulsifying salt in this combination being from about 1:6 to about 1:4; and the balance of the emulsion to make by weight being water.

2. An oil-in-water type paving bituminous emulsion as defined in claim 1, wherein the cation-active salt component of the emulsifier is a quaternary ammonium salt of oleylamine ethoxylated with two moles of ethylene oxide, and the ampholytic salt component is a sodium salt of N-lauryl beta-infinodipropionic acid.

References Cited UNITED STATES PATENTS 5/1934 Loebel 252-311.5 4/1955 Sommer et a1. 252311.5 X

OTHER REFERENCES LEON D. ROSDOL, Primary Examiner. R. D. LOVERING, Assistant Examiner.

US. Cl. X.R. 

